Geminate and nongeminate recombination of triplet excitons formed by singlet fission.
| Author | |
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| Abstract | :
We report the simultaneous observation of geminate and nongeminate triplet-triplet annihilation in a solution-processable small molecule TIPS-tetracene undergoing singlet exciton fission. Using optically detected magnetic resonance, we identify recombination of triplet pairs directly following singlet fission, as well as recombination of triplet excitons undergoing bimolecular triplet-triplet annihilation. We show that the two processes give rise to distinct magnetic resonance spectra, and estimate the interaction between geminate triplet excitons to be 60 neV. |
| Year of Publication | :
2014
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| Journal | :
Physical review letters
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| Volume | :
112
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| Issue | :
23
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| Number of Pages | :
238701
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| Date Published | :
2014
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| ISSN Number | :
0031-9007
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| URL | :
https://link.aps.org/abstract/PRL/v112/p238701
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| DOI | :
10.1103/PhysRevLett.112.238701
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| Short Title | :
Phys Rev Lett
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